Here is an example COSHH Document we supplied to one of our commercial customers which is required by law before any cleaning work can be carried out

 

SAFETY DATA SHEET

 

BIOSHIELD LEMON                                                                                  Page 1

 

Issued: 01/08/2008

 

Revision No: 3

 

1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING

 

Product name:   BIOSHIELD LEMON

 

Product code:    205

 

Use of substance / preparation:   205 : A thick, fragrant, bactericidal washroom cleaner that controls water scale. Available in lemon, lime, and floral fragrances.

Company name:   Clover Chemicals Ltd Clover House Macclesfield Road

Whaley Bridge, High Peak

 

Derbyshire SK23 7DQ UK

Tel: +44 (0) 1663 733114

 

Fax: +44 (0) 1663 733115

 

Email:technical@cloverchemicals.com

 

2. HAZARDS IDENTIFICATION

 

Main hazards:   Irritating to eyes.

 

3. COMPOSITION / INFORMATION ON INGREDIENTS

 

Hazardous ingredients:   SULPHAMIC ACID  0-1%

 

EINECS: 226-218-8   CAS: 5329-14-6 [Xi] R36/38;  [-] R52/53

•    (C9 – C18)PARETH(2 – 18)  1-10%

 

•    /-ALKYLDIMETHYLBENZYLAMMONIUM CHLORIDE  1-10% EINECS: 269-919-4

[Xn] R22;  [C] R34

 

4. FIRST AID MEASURES (SYMPTOMS)

 

Skin contact:   There may be irritation and redness at the site of contact.

 

Eye contact:   There may be pain and redness. The eyes may water profusely. There may be severe pain. The vision may become blurred. May cause permanent damage.

Ingestion:   There may be soreness and redness of the mouth and throat. Nausea and stomach pain may occur.

Inhalation:   There may be irritation of the throat with a feeling of tightness in the chest.

 

4. FIRST AID MEASURES (ACTION)

Skin contact:   Remove all contaminated clothes and footwear immediately unless stuck to skin. Wash immediately with plenty of soap and water.

 

[cont…]

Issued: 01/08/2008


SAFETY DATA SHEET

BIOSHIELD LEMON                                                                                  Page 2

 

Eye contact:   Bathe the eye with running water for 15 minutes. Transfer to hospital for specialist examination.

 

Ingestion:   Wash out mouth with water. Do not induce vomiting. If conscious, give half a litre of water to drink immediately. Transfer to hospital as soon as possible.

Inhalation:   Transfer to hospital as soon as possible.

 

5. FIRE-FIGHTING MEASURES

 

Extinguishing media:   Suitable extinguishing media for the surrounding fire should be used. Use water spray to cool containers.

Exposure hazards:   In combustion emits toxic fumes.

Protection of fire-fighters:   Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes.

 

6. ACCIDENTAL RELEASE MEASURES

 

Personal precautions:   Mark out the contaminated area with signs and prevent access to unauthorised personnel. Do not attempt to take action without suitable protective clothing – see section 8 of SDS. Turn leaking containers leak-side up to prevent the escape of liquid.

Environmental precautions:   Do not discharge into drains or rivers. Contain the spillage using bunding.

Clean-up procedures:   Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal by an appropriate method.

 

7. HANDLING AND STORAGE

 

Handling requirements:   Avoid direct contact with the substance. Ensure there is sufficient ventilation of the area. Avoid the formation or spread of mists in the air.

Storage conditions:   Store in cool, well ventilated area. Keep container tightly closed.

 

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

 

Respiratory protection:   Respiratory protection not required.

 

Hand protection:   Rubber gloves.

 

Eye protection:   Ensure eye bath is to hand.

 

Skin protection:   Protective clothing.

 

9. PHYSICAL AND CHEMICAL PROPERTIES

 

State:    Liquid

 

Colour:    Yellow

 

Odour:   Characteristic odour

 

Evaporation rate:   Moderate

 

Solubility in water:   Soluble

 

Viscosity:    Viscous

 

Relative density:   0.97 – 1.07

 

pH:   1% = 3 – 3.5

 

 

[cont…]

Issued: 01/08/2008

SAFETY DATA SHEET

BIOSHIELD LEMON                                                                                  Page 3

VOC g/l:   4

 

10. STABILITY AND REACTIVITY

 

Stability:    Stable under normal conditions.

 

Conditions to avoid:   Heat.

 

Materials to avoid:   Strong oxidising agents. Strong acids.

 

Haz. decomp. products:   In combustion emits toxic fumes.

 

11. TOXICOLOGICAL INFORMATION

 

Hazardous ingredients:   SULPHAMIC ACID

 

IPR RAT LDLO 100 mg/kg ORL MUS LD50 1312 mg/kg ORL RAT LD50 3160 mg/kg

Routes of exposure:   Refer to section 4 of SDS for routes of exposure and corresponding symptoms.

 

12. ECOLOGICAL INFORMATION

 

Mobility:    Readily absorbed into soil.

 

Persistence and degradability:   Biodegradable.

 

Bioaccumulative potential:   No bioaccumulation potential.

 

Other adverse effects:   Negligible ecotoxicity.

 

13. DISPOSAL CONSIDERATIONS

 

Disposal of packaging:   Dispose of as normal industrial waste.

NB:   The user’s attention is drawn to the possible existence of regional or national regulations regarding disposal.

 

14. TRANSPORT INFORMATION

 

ADR / RID

 

UN no:   Not Classified.

 

IMDG / IMO

 

UN no:   Not Classified.

 

IATA / ICAO

 

UN no:   Not Classified.

 

15. REGULATORY INFORMATION

 

Hazard symbols:   Irritant.

Risk phrases:   R36: Irritating to eyes.

 

[cont…]

Issued: 01/08/2008


SAFETY DATA SHEET

BIOSHIELD LEMON                                                                                  Page 4

 

Safety phrases:   S2: Keep out of the reach of children.

 

S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

Precautionary phrases:    Use biocides safely. Always read the label and product information before use.

 

Seveso II guideline:   No

 

Water hazard class:   1 Classification by VwVwS

 

Air emission directive:   Amount m%:  0

 

Note:    The regulatory information given above only indicates the principal regulations specifically applicable to the product described in the safety data sheet. The user’s attention is drawn to the possible existence of additional provisions which complete these regulations. Refer to all

applicable national, international and local regulations or provisions.

 

16. OTHER INFORMATION

 

Risk phrases used in s.3:   R36/38: Irritating to eyes and skin.

 

R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

R22: Harmful if swallowed. R34: Causes burns.

Legal disclaimer:   The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from

handling or from contact with the above product.

 

DIRECTIONS OF USE FOR BIO SHIELD WASHROOM CLEANER

 

Use undiluted on heavy soil. For light to medium soiling, apply a diluted

solution using a mop and bucket, trigger spray or cloth. Wear rubber gloves

when using Bio-Shield undiluted for any length of time. Apply to the surface,

agitate and rinse or wipe away for a smear-free finish.

 

[final page]

SAFETY DATA SHEET

 

CREAM CLEANER                                                                                   Page 1

 

Issued: 01/08/2008

 

Revision No: 3

 

 

1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING

 

Product name:   CREAM CLEANER

 

Product code:    431

 

Use of substance / preparation:   431 :

 

Company name:   Clover Chemicals Ltd

 

2. HAZARDS IDENTIFICATION

 

Main hazards:   No significant hazard.

3. COMPOSITION / INFORMATION ON INGREDIENTS

 

Hazardous ingredients:   (C9 – C18)PARETH(2 – 18)  <1%

4. FIRST AID MEASURES (SYMPTOMS)

 

Skin contact:   No symptoms.

 

Eye contact:   There may be irritation and redness.

 

Ingestion:   No symptoms.

 

Inhalation:   No symptoms.

4. FIRST AID MEASURES (ACTION)

 

Skin contact:   Wash immediately with plenty of soap and water.

 

Eye contact:   Bathe the eye with running water for 15 minutes.

Ingestion:   Do not induce vomiting. If conscious, give half a litre of water to drink immediately. Transfer to hospital as soon as possible.

 

5. FIRE-FIGHTING MEASURES

 

Extinguishing media:   Water.

 

Exposure hazards:   In combustion emits toxic fumes of carbon dioxide / carbon monoxide.

 

Protection of fire-fighters:   Wear self-contained breathing apparatus.

 

6. ACCIDENTAL RELEASE MEASURES

 

Personal precautions:   Refer to section 8 of SDS for personal protection details.

 

Environmental precautions:   Do not discharge into drains or rivers

[cont…]

Issued: 01/08/2008


SAFETY DATA SHEET

CREAM CLEANER                                                                                   Page 2

 

Clean-up procedures:   Wash the spillage site with large amounts of water.

 

7. HANDLING AND STORAGE

 

Suitable packaging:   Aluminium containers. Stainless steel. Polyethylene.

 

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

 

9. PHYSICAL AND CHEMICAL PROPERTIES

 

State:    Liquid Colour:    Off-white Odour:    Pleasant

Evaporation rate:   Moderate

 

Oxidising:    Non-oxidising (by EC criteria)

 

Solubility in water:    Miscible

 

Viscosity:    Viscous

 

Relative density:   1.3

 

pH:   10 – 10.5

 

10. STABILITY AND REACTIVITY

 

Stability:    Stable under normal conditions.

 

Materials to avoid:   Strong oxidising agents.

 

11. TOXICOLOGICAL INFORMATION

 

12. ECOLOGICAL INFORMATION

 

Mobility:    Non-volatile.

 

Persistence and degradability:   Biodegradable.

 

Bioaccumulative potential:   No bioaccumulation potential.

 

13. DISPOSAL CONSIDERATIONS

 

Disposal of packaging:   Dispose of as normal industrial waste.

NB:   The user’s attention is drawn to the possible existence of regional or national regulations regarding disposal.

 

14. TRANSPORT INFORMATION

 

ADR / RID

 

UN no:   Not Classified.

 

IMDG / IMO

 

UN no:   Not Classified.

 

[cont…]

Issued: 01/08/2008


SAFETY DATA SHEET

CREAM CLEANER                                                                                   Page 3

 

 

IATA / ICAO

 

UN no:   Not Classified.

 

15. REGULATORY INFORMATION

 

Hazard symbols:   No significant hazard.

 

Safety phrases:   S2: Keep out of the reach of children.

 

S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

Seveso II guideline:   No

 

Water hazard class:   1 Classification by VwVwS

 

Note:    The regulatory information given above only indicates the principal regulations specifically applicable to the product described in the safety data sheet. The user’s attention is drawn to the possible existence of additional provisions which complete these regulations. Refer to all

applicable national, international and local regulations or provisions.

 

16. OTHER INFORMATION

 

Legal disclaimer:   The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from

handling or from contact with the above product.

 

DIRECTIONS OF USE FOR CREAM CLEANER

 

Use undiluted. Squeeze a little CREAM CLEANER onto a damp cloth, apply to

the surface to be cleaned and wipe gently. Agitate to remove any stubborn

stains. Wipe dry for a real shine.

 

[final page]

SAFETY DATA SHEET

 

PRESTIGE                                                                                          Page 1

 

Issued: 01/08/2008

 

Revision No: 3

 

1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING

 

Product name:   PRESTIGE

 

Product code:    601

 

Use of substance / preparation:   601 : A ready to use wax based furniture polish designed to clean , freshen and create a gloss shine.

Company name:   Clover Chemicals Ltd Clover House Macclesfield Road

Whaley Bridge, High Peak

 

Derbyshire SK23 7DQ UK

Tel: +44 (0) 1663 733114

 

Fax: +44 (0) 1663 733115

 

Email:technical@cloverchemicals.com

 

2. HAZARDS IDENTIFICATION

 

Main hazards:   No significant hazard.

3. COMPOSITION / INFORMATION ON INGREDIENTS

4. FIRST AID MEASURES (SYMPTOMS)

 

Skin contact:   No symptoms.

 

Eye contact:   There may be irritation and redness.

 

Ingestion:   No symptoms.

 

Inhalation:   There may be irritation of the throat with a feeling of tightness in the chest.

 

4. FIRST AID MEASURES (ACTION)

 

Skin contact:   Wash immediately with plenty of soap and water.

 

Eye contact:   Bathe the eye with running water for 15 minutes.

 

Ingestion:   If conscious, give half a litre of water to drink immediately. Transfer to hospital as soon as possible.

Inhalation:   Transfer to hospital as soon as possible.

 

5. FIRE-FIGHTING MEASURES

 

Extinguishing media:   Water.

 

Exposure hazards:   In combustion emits toxic fumes of carbon dioxide.

 

Protection of fire-fighters:   Wear self-contained breathing apparatus.

[cont…]

Issued: 01/08/2008


SAFETY DATA SHEET

PRESTIGE                                                                                           Page 2

 

6. ACCIDENTAL RELEASE MEASURES

 

Personal precautions:   Refer to section 8 of SDS for personal protection details.

 

Environmental precautions:   Do not discharge into drains or rivers.

 

Clean-up procedures:   Absorb into dry earth or sand.

 

7. HANDLING AND STORAGE

 

Suitable packaging:   Aluminium containers. Stainless steel. Polyethylene.

 

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

 

9. PHYSICAL AND CHEMICAL PROPERTIES

 

State:    Liquid Colour:   Off-white Odour:    Sweet-smelling

Evaporation rate:    Moderate

 

Oxidising:    Non-oxidising (by EC criteria)

 

Solubility in water:    Miscible

 

Viscosity:    Non-viscous

 

Relative density:   0.98 – 0.985

 

pH:   5.2 – 6.0

 

VOC g/l:    50

 

10. STABILITY AND REACTIVITY

 

Stability:    Stable under normal conditions.

 

Materials to avoid:   Strong oxidising agents.

 

Haz. decomp. products:   In combustion emits toxic fumes of carbon dioxide.

 

11. TOXICOLOGICAL INFORMATION

 

12. ECOLOGICAL INFORMATION

 

Mobility:    Floats on water.

 

Bioaccumulative potential:   No bioaccumulation potential.

 

13. DISPOSAL CONSIDERATIONS

 

Disposal of packaging:   Dispose of as normal industrial waste.

NB:   The user’s attention is drawn to the possible existence of regional or national regulations regarding disposal.

 

14. TRANSPORT INFORMATION

 

ADR / RID

 

UN no:   Not Classified.

 

[cont…]

Issued: 01/08/2008

SAFETY DATA SHEET

PRESTIGE                                                                                           Page 3

IMDG / IMO

 

UN no:   Not Classified.

 

IATA / ICAO

 

UN no:   Not Classified.

 

15. REGULATORY INFORMATION

 

Hazard symbols:   No significant hazard.

 

Safety phrases:   S2: Keep out of the reach of children.

 

Seveso II guideline:   No

 

Water hazard class:   1 Classification by VwVwS

 

Note:    The regulatory information given above only indicates the principal regulations specifically applicable to the product described in the safety data sheet. The user’s attention is drawn to the possible existence of additional provisions which complete these regulations. Refer to all

applicable national, international and local regulations or provisions.

 

16. OTHER INFORMATION

 

Legal disclaimer:   The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from

handling or from contact with the above product

 

DIRECTIONS OF USE FOR PRESTIGE FURNITURE POLISH

 

Shake the bottle well before use. Spray lightly onto the surface to be cleaned

and wipe immediately with a soft cloth for a deep shine and protective finish.

Turn the cloth frequently for best results. For difficult areas, apply onto the

cloth before wiping the surface.

[final page]

SAFETY DATA SHEET

 

SAVON PEARLE                                                                                     Page 1

 

Issued: 03/11/2009

 

Revision No: 4

 

1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING

 

Product name:   SAVON PEARLE

 

Product code:    402

 

Use of substance / preparation:   402 : A fragrant, mild, pink pearlised liquid soap that creates a rich foam and gently cleanses the skin.

Company name:   Clover Chemicals Ltd Clover House Macclesfield Road

Whaley Bridge, High Peak

 

Derbyshire SK23 7DQ UK

Tel: +44 (0) 1663 733114

 

Fax: +44 (0) 1663 733115

 

Email:technical@cloverchemicals.com

2. HAZARDS IDENTIFICATION

3. COMPOSITION / INFORMATION ON INGREDIENTS

 

Hazardous ingredients:   COCAMIDODIPROPYL BETAINE  1-10% [Xi] R36

•    AMMONIUM LAURYL SULPHATE  1-10% CAS: 2235-54-3

[Xi] R36/38

 

•    SODIUM, ALKYL C10-18, ETHER SULPHATE  1-10% CAS: 102783-14-2

[Xi] R38;  [Xi] R41

4. FIRST AID MEASURES (SYMPTOMS)

 

Skin contact:   No symptoms.

Eye contact:   There may be irritation and redness. Ingestion:   There may be irritation of the throat. Inhalation:   No symptoms.

4. FIRST AID MEASURES (ACTION)

 

Eye contact:   Bathe the eye with running water for 15 minutes.

 

Ingestion:   Wash out mouth with water.

 

Inhalation:   Consult a doctor.

[cont…]

Issued: 03/11/2009


SAFETY DATA SHEET

SAVON PEARLE                                                                                     Page 2

 

5. FIRE-FIGHTING MEASURES

 

Extinguishing media:   Suitable extinguishing media for the surrounding fire should be used. Use water spray to cool containers.

Exposure hazards:   In combustion emits toxic fumes.

 

Protection of fire-fighters:   Wear self-contained breathing apparatus.

 

6. ACCIDENTAL RELEASE MEASURES

 

Personal precautions:   Refer to section 8 of SDS for personal protection details. Turn leaking containers leak-side up to prevent the escape of liquid.

Environmental precautions:   Do not discharge into drains or rivers. Contain the spillage using bunding.

Clean-up procedures:   Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal by an appropriate method.

 

7. HANDLING AND STORAGE

 

Storage conditions:   Store in cool, well ventilated area. Keep container tightly closed.

 

Suitable packaging:   Polyethylene. Stainless steel. Glass.

 

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

 

Respiratory protection:   Respiratory protection not required.

 

9. PHYSICAL AND CHEMICAL PROPERTIES

 

State:    Liquid Colour:   Pink Odour:    Pleasant

Evaporation rate:    Moderate

 

Oxidising:    Non-oxidising (by EC criteria)

 

Solubility in water:    Soluble

 

Viscosity:    Viscous

 

Boiling point/range°C:   98 – 102

 

Melting point/range°C:   -2 /0

 

Relative density:    1.023

 

pH:   6.5 – 7.5

 

VOC g/l:   0

 

10. STABILITY AND REACTIVITY

 

Stability:    Stable under normal conditions.

 

Conditions to avoid:   Heat.

 

Haz. decomp. products:   In combustion emits toxic fumes of carbon dioxide.

 

[cont…

Issued: 03/11/2009


SAFETY DATA SHEET

SAVON PEARLE                                                                                     Page 3

 

11. TOXICOLOGICAL INFORMATION

 

Hazardous ingredients:   COCAMIDODIPROPYL BETAINE ORL RAT LD50 >2000 mg/kg

•    SODIUM, ALKYL C10-18, ETHER SULPHATE ORL RAT LD50 >2000 mg/kg

Routes of exposure:   Refer to section 4 of SDS for routes of exposure and corresponding symptoms.

 

12. ECOLOGICAL INFORMATION

 

Hazardous ingredients:   COCAMIDODIPROPYL BETAINE BACTERIA Ps Puteda 48H EC50 >1000 mg/l FISH  96H LC50 1 – 10 mg/l

Mobility:    Readily absorbed into soil.

 

Persistence and degradability:   Biodegradable. The surfactants contained in this preperation comply with the biodegradability criteria as laid down in regulation (EC) No.648/2004 on detergents.

Bioaccumulative potential:   No bioaccumulation potential.

 

Other adverse effects:   Negligible ecotoxicity.

 

13. DISPOSAL CONSIDERATIONS

 

Disposal of packaging:   Dispose of as normal industrial waste.

NB:   The user’s attention is drawn to the possible existence of regional or national regulations regarding disposal.

 

14. TRANSPORT INFORMATION

 

ADR / RID

 

UN no:   Not Classified.

 

IMDG / IMO

 

UN no:   Not Classified.

 

IATA / ICAO

 

UN no:   Not Classified.

 

15. REGULATORY INFORMATION

 

                                                Haz. ingredients (label):   SODIUM, ALKYL C10-18, ETHER SULPHATE

 

Seveso II guideline:   No

 

Water hazard class:   1 Classification by VwVwS

 

Air emission directive:   Amount m%:  0

 

Note:    The regulatory information given above only indicates the principal regulations specifically applicable to the product described in the safety data sheet. The user’s attention is drawn to the possible existence of additional provisions which complete these regulations. Refer to all applicable national, international and local regulations or provisions.


 

 

 

 

 

 

 

 

 

 

 

 

[cont…]

 

Issued: 03/11/2009


SAFETY DATA SHEET

SAVON PEARLE                                                                                     Page 4

 

 

 

 

 

 

16. OTHER INFORMATION

 

Risk phrases used in s.3:   R36: Irritating to eyes.

 

R36/38: Irritating to eyes and skin. R38: Irritating to skin.

R41: Risk of serious damage to eyes.

 

Legal disclaimer:   The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from

handling or from contact with the above product.

 

 

 

 

 

 

 

 

 

 

 

DIRECTIONS OF USE FOR FOR SAVON PEARLE

 

Used undiluted through most recognised dispensers. Simply dispense onto hands, add water, work up a good lather and rinse off, leaving the skin feeling clean and refreshed.

final page]

SAFETY DATA SHEET

 

THICK BLEACH                                                                                     Page 1

 

Issued: 01/08/2009

 

Revision No: 2

 

1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING

 

Product name:   THICK BLEACH

 

Product code:    215

 

Use of substance / preparation:   215: A concentrated,viscous industrial bleach solution,effective against bacteria.Contains < 5%

 

available chlorine.

 

Company name:   Clover Chemicals Ltd Clover House Macclesfield Road

Whaley Bridge, High Peak

 

Derbyshire SK23 7DQ UK

Tel: +44 (0) 1663 733114

 

Fax: +44 (0) 1663 733115

 

Email:technical@cloverchemicals.com

2. HAZARDS IDENTIFICATION

 

Main hazards:   Irritating to eyes and skin.

 

Other hazards:   Contact with acids liberates toxic gas.

3. COMPOSITION / INFORMATION ON INGREDIENTS

 

Hazardous ingredients:   SODIUM HYPOCHLORITE SOLUTION CL ACTIVE  1-10% EINECS: 231-668-3   CAS: 7681-52-9

[-] R31;  [C] R34;  [N] R50

 

•    /-COCODIMETHYLAMINE OXIDE  1-10% CAS: 61788-90-7

[N] R50;  [Xi] R36/38

 

•    /- ANIONIC SURFACTANT  1-10% [Xi] R36/38

•    AMPHOTERIC SURFACTANT  1-10% EINECS: )

[Xi] R36

 

4. FIRST AID MEASURES (SYMPTOMS)

 

Skin contact:   Blistering may occur. Progressive ulceration will occur if treatment is not immediate.

 

Eye contact:   Corneal burns may occur. May cause permanent damage.

 

Ingestion:   Corrosive burns may appear around the lips. Blood may be vomited. There may be bleeding from the mouth or nose.

Inhalation:   There may be shortness of breath with a burning sensation in the throat. Exposure may cause

 

coughing or wheezing.                                                                                                                                    [cont…]

 

Issued: 01/08/2009

SAFETY DATA SHEET

THICK BLEACH                                                                                     Page 2

4. FIRST AID MEASURES (ACTION)

Skin contact:   Remove all contaminated clothes and footwear immediately unless stuck to skin. Drench the affected skin with running water for 10 minutes or longer if substance is still on skin. Transfer to hospital if there are burns or symptoms of poisoning.

Eye contact:   Bathe the eye with running water for 15 minutes. Transfer to hospital for specialist examination.

Ingestion:   Wash out mouth with water. Do not induce vomiting. Give 1 cup of water to drink every 10 minutes. If unconscious, check for breathing and apply artificial respiration if necessary. If unconscious and breathing is OK, place in the recovery position. Transfer to hospital as soon as possible.

Inhalation:   Remove casualty from exposure ensuring one’s own safety whilst doing so. If unconscious and breathing is OK,  place in the recovery position. If conscious, ensure the casualty sits or lies down. If breathing becomes bubbly, have the casualty sit and provide oxygen if available.

Transfer to hospital as soon as possible.

5. FIRE-FIGHTING MEASURES

Extinguishing media:   Suitable extinguishing media for the surrounding fire should be used. Use water spray to cool containers.

Exposure hazards:   Corrosive. In combustion emits toxic fumes.

Protection of fire-fighters:   Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions:   Notify the police and fire brigade immediately. If outside keep bystanders upwind and away from danger point. Mark out the contaminated area with signs and prevent access to unauthorised personnel. Do not attempt to take action without suitable protective clothing – see section 8 of SDS. Turn leaking containers leak-side up to prevent the escape of liquid.

Environmental precautions:   Do not discharge into drains or rivers. Contain the spillage using bunding.

Clean-up procedures:   Clean-up should be dealt with only by qualified personnel familiar with the specific substance.

Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal by an appropriate method.

7. HANDLING AND STORAGE

Handling requirements:   Avoid direct contact with the substance. Ensure there is sufficient ventilation of the area. Do not handle in a confined space. Avoid the formation or spread of mists in the air.

Storage conditions:   Store in cool, well ventilated area. Keep container tightly closed.

Suitable packaging:   Polyethylene.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

                              Hazardous ingredients:   SODIUM HYPOCHLORITE SOLUTION…100% CL ACTIVE WEL (8 hr TWA): 1.5mg/m3

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Engineering measures:   Ensure there is sufficient ventilation of the area.

 

Respiratory protection:   Self-contained breathing apparatus must be available in case of emergency.

 

Hand protection:   Impermeable gloves. Rubber gloves. Gloves (alkali-resistant).

 

Eye protection:   Tightly fitting safety goggles. Ensure eye bath is to hand.

 

Skin protection:   Impermeable protective clothing.

 

9. PHYSICAL AND CHEMICAL PROPERTIES

 

State:    Liquid

 

Colour:   Pale yellow

 

Odour:   Characteristic odour

 

Evaporation rate:    Moderate

 

Oxidising:    Oxidising (by EC criteria)

 

Solubility in water:   Soluble

 

Viscosity:    Viscous

 

Relative density:   1.05 – 1.15

 

pH:   12

 

VOC g/l:   0

 

10. STABILITY AND REACTIVITY

 

Stability:    Stable under normal conditions.

 

Conditions to avoid:   Heat.

 

Materials to avoid:   Strong oxidising agents. Strong acids.

 

Haz. decomp. products:   In combustion emits toxic fumes.

 

11. TOXICOLOGICAL INFORMATION

 

Hazardous ingredients:   SODIUM HYPOCHLORITE SOLUTION…100% CL ACTIVE ORL RAT LD50 750 mg/kg

•    /- ANIONIC SURFACTANT ORL RAT LD50 >2000 mg/kg

Routes of exposure:   Refer to section 4 of SDS for routes of exposure and corresponding symptoms.

 

12. ECOLOGICAL INFORMATION

 

Hazardous ingredients:   SODIUM HYPOCHLORITE SOLUTION…100% CL ACTIVE FISH  LC100 1 mg/l

Mobility:    Readily absorbed into soil.

 

Persistence and degradability:   Biodegradable. The surfactants contained in this preperation comply with the biodegradability criteria as laid down in regulation (EC) No.648/2004 on detergents.

Bioaccumulative potential:   No bioaccumulation potential.

 

Other adverse effects:   Toxic to aquatic organisms.

 

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13. DISPOSAL CONSIDERATIONS

 

Disposal of packaging:   Dispose of as normal industrial waste.

NB:   The user’s attention is drawn to the possible existence of regional or national regulations regarding disposal.

 

14. TRANSPORT INFORMATION

 

ADR / RID

 

UN no:   Not Classified.

 

IMDG / IMO

 

UN no:   Not Classified.

 

IATA / ICAO

 

UN no:   Not Classified.

 

15. REGULATORY INFORMATION

 

Hazard symbols:   Irritant.

 

 

 

Risk phrases:   R36/38: Irritating to eyes and skin.

 

Safety phrases:   S1/2: Keep locked up and out of the reach of children.

 

S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

Precautionary phrases:    Warning! Do not use with other products. May release dangerous gases (chlorine).

 

Use biocides safely. Always read the label and product information before use.

 

Seveso II guideline:   No

 

Water hazard class:   2 Classification by VwVwS

 

Note:    The regulatory information given above only indicates the principal regulations specifically applicable to the product described in the safety data sheet. The user’s attention is drawn to the possible existence of additional provisions which complete these regulations. Refer to all

applicable national, international and local regulations or provisions.

 

16. OTHER INFORMATION

 

Risk phrases used in s.3:   R31: Contact with acids liberates toxic gas.

 

R34: Causes burns.

 

R50: Very toxic to aquatic organisms. R36/38: Irritating to eyes and skin. R36: Irritating to eyes.

Legal disclaimer:   The above information is believed to be correct but does not purport to be all inclusive and shall

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THICK BLEACH                                                                                     Page 5

 

be used only as a guide. This company shall not be held liable for any damage resulting from

 

handling or from contact with the above product.

 

DIRECTIONS OF USE FOR THICK BLEACH

 

Use undiluted to disinfect drains, toilets and waste pipes.

For general disinfection, dilute at a ratio of 1 part to 120 parts water. Apply using a mop

or cloth, allow a few minutes contact time, agitate and rinse away.

N.B. Handle with care – splashes can cause damage to some floors and fabrics. Never

mix THICK BLEACH with other chemicals.

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